Bis[(diphenyl­phosphanylmeth­yl)diphenyl­phosphane sulfide-κ2 P,S]copper(I) hexa­fluoridophosphate

نویسندگان

  • Jing-Jing Zhang
  • Feng Hu
  • Tai-Ke Duan
  • Qun Chen
  • Qian-Feng Zhang
چکیده

In the title compound, [Cu(C(25)H(22)P(2)S)(2)]PF(6), the Cu(I) atom, lying on a twofold rotation axis, adopts a distorted tetra-hedral geometry. The (diphenyl-phosphanylmeth-yl)diphenyl-phos-phane sulfide ligand coordinates to the Cu(I) atom through one S and one P atom, forming a stable five-membered chelate ring. The P atom of the PF(6) (-) anion also lies on a twofold rotation axis.

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عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012